Electrophilicity-Nucleophilicity Scale Also in the Gas Phase

Chagit Denekamp; Yana Sandlers

doi:10.1002/anie.200503235

Electrophilicity-Nucleophilicity Scale Also in the Gas Phase

Chagit Denekamp
, Yana Sandlers

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Changing the state: The electrophilicity of benzhydryl cations (see formula) towards neutral amine nucleophiles in the gas phase was determined. It was found that the kinetics of electrophile-nucleophile gas-phase reactions correlate well with values known in solution although the actual electrophilicity parameters are considerably smaller in the gas phase. (Chemical Equation Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	American English
Journal	Angewandte Chemie - International Edition
Volume	45
DOIs	https://doi.org/10.1002/anie.200503235
State	Published - Mar 20 2006
Externally published	Yes

Keywords

Electrophilicity
Ion-molecule reactions
Kinetics
Linear free-energy relationships
Mass spectrometry

Disciplines

Chemistry

Access to Document

10.1002/anie.200503235License: CC BY

https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200503235

Cite this

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title = "Electrophilicity-Nucleophilicity Scale Also in the Gas Phase",

abstract = " Changing the state: The electrophilicity of benzhydryl cations (see formula) towards neutral amine nucleophiles in the gas phase was determined. It was found that the kinetics of electrophile-nucleophile gas-phase reactions correlate well with values known in solution although the actual electrophilicity parameters are considerably smaller in the gas phase. (Chemical Equation Presented) {\textcopyright} 2006 Wiley-VCH Verlag GmbH \& Co. KGaA.",

keywords = "Electrophilicity, Ion-molecule reactions, Kinetics, Linear free-energy relationships, Mass spectrometry",

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T1 - Electrophilicity-Nucleophilicity Scale Also in the Gas Phase

AU - Denekamp, Chagit

AU - Sandlers, Yana

PY - 2006/3/20

Y1 - 2006/3/20

N2 - Changing the state: The electrophilicity of benzhydryl cations (see formula) towards neutral amine nucleophiles in the gas phase was determined. It was found that the kinetics of electrophile-nucleophile gas-phase reactions correlate well with values known in solution although the actual electrophilicity parameters are considerably smaller in the gas phase. (Chemical Equation Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - Changing the state: The electrophilicity of benzhydryl cations (see formula) towards neutral amine nucleophiles in the gas phase was determined. It was found that the kinetics of electrophile-nucleophile gas-phase reactions correlate well with values known in solution although the actual electrophilicity parameters are considerably smaller in the gas phase. (Chemical Equation Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Electrophilicity

KW - Ion-molecule reactions

KW - Kinetics

KW - Linear free-energy relationships

KW - Mass spectrometry

UR - https://engagedscholarship.csuohio.edu/scichem_facpub/542

UR - https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200503235

U2 - 10.1002/anie.200503235

DO - 10.1002/anie.200503235

M3 - Article

VL - 45

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

ER -

Electrophilicity-Nucleophilicity Scale Also in the Gas Phase

Abstract

Keywords

Disciplines

Access to Document

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