Observation of the Transition from Semiconductor to High-Tc Superconductor in (SnxEu1-X)YMo6S8 Under High Pressure

D. W. Harrison, K. C. Lim, J. D. Thompson, C. Y. Huang, Paul D. Hambourger, H. L. Luo

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    Abstract

    <p> Pressure-induced high-temperature superconductivity is observed in semiconducting (Sn <sub> x </sub> Eu <sub> 1-x </sub> ) <sub> y </sub> Mo <sub> 6 </sub> S <sub> 8 </sub> , where 0&lt;~x&lt;~0.1 and y=1.0 and 1.2, having a carrier concentration &simeq;10 <sup> 19 </sup> /cm <sup> 3 </sup> at 4.2 K as determined from Hall-effect measurements. Above a threshold pressure &simeq;7 kbar, superconductivity appears with dT <sub> c </sub> /dP&simeq;2 K/kbar. The maximum superconducting temperature (T <sub> c </sub> &sim;10 K), reached at &sim; 12 kbar, represents the highest pressure-induced T <sub> c </sub> in any semiconductor. For P&gt;~13 kbar, the temperature-dependent resistance appears metallic.</p>
    Original languageAmerican English
    JournalPhysical Review Letters
    Volume46
    DOIs
    StatePublished - Jan 26 1981

    Disciplines

    • Physics

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