Satellite transition rotational resonance of homonuclear quadrupolar spins: magic-angle effect on spin-echo decay and inversion recovery

Hyung-Tae Kwak; Partha Srinivasan; John R Quine; Dominique Massiot; Zhehong Gan

Satellite transition rotational resonance of homonuclear quadrupolar spins: magic-angle effect on spin-echo decay and inversion recovery

Hyung-Tae Kwak
, Partha Srinivasan
, John R Quine
, Dominique Massiot
, Zhehong Gan

Florida State University

Research output: Contribution to journal › Article › peer-review

Abstract

Satellite transition rotational resonance and magic-angle effects on central-transition spin-echo decay and inversion recovery of half-integer quadrupolar nuclei are presented. Small magic-angle offsets can change the satellite transition rotational resonance condition and consequently lead to dramatic effects on line width, spin-echo decay and inversion recovery. An half degree magic-angle offset lengthens α-Al2O3 spin-echo decay by 50% and inversion-recovery by nearly two orders of magnitude. The theory of satellite transition rotational resonance is presented and the origin of these magic-angle effects is explained.

Original language	American English
Journal	Chemical Physics Letters
Volume	376
State	Published - Jul 17 2003

Keywords

Quadrupolar nuclei
STMAS

Disciplines

Physical Chemistry

Cite this

@article{1a5d4af24ef341f1aae156587b998409,

title = "Satellite transition rotational resonance of homonuclear quadrupolar spins: magic-angle effect on spin-echo decay and inversion recovery",

abstract = " Satellite transition rotational resonance and magic-angle effects on central-transition spin-echo decay and inversion recovery of half-integer quadrupolar nuclei are presented. Small magic-angle offsets can change the satellite transition rotational resonance condition and consequently lead to dramatic effects on line width, spin-echo decay and inversion recovery. An half degree magic-angle offset lengthens α-Al2O3 spin-echo decay by 50\% and inversion-recovery by nearly two orders of magnitude. The theory of satellite transition rotational resonance is presented and the origin of these magic-angle effects is explained.",

keywords = "Quadrupolar nuclei, STMAS",

author = "Hyung-Tae Kwak and Partha Srinivasan and Quine, \{John R\} and Dominique Massiot and Zhehong Gan",

note = "Satellite transition rotational resonance and magic-angle effects on central-transition spin-echo decay and inversion recovery of half-integer quadrupolar nuclei are presented. Small magic-angle offsets can change the satellite transition rotational resonance condition and consequently lead to dramatic effects on line width, spin-echo decay and inversion recovery.",

year = "2003",

month = jul,

day = "17",

language = "American English",

volume = "376",

journal = "Chemical Physics Letters",

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TY - JOUR

T1 - Satellite transition rotational resonance of homonuclear quadrupolar spins: magic-angle effect on spin-echo decay and inversion recovery

AU - Kwak, Hyung-Tae

AU - Srinivasan, Partha

AU - Quine, John R

AU - Massiot, Dominique

AU - Gan, Zhehong

N1 - Satellite transition rotational resonance and magic-angle effects on central-transition spin-echo decay and inversion recovery of half-integer quadrupolar nuclei are presented. Small magic-angle offsets can change the satellite transition rotational resonance condition and consequently lead to dramatic effects on line width, spin-echo decay and inversion recovery.

PY - 2003/7/17

Y1 - 2003/7/17

N2 - Satellite transition rotational resonance and magic-angle effects on central-transition spin-echo decay and inversion recovery of half-integer quadrupolar nuclei are presented. Small magic-angle offsets can change the satellite transition rotational resonance condition and consequently lead to dramatic effects on line width, spin-echo decay and inversion recovery. An half degree magic-angle offset lengthens α-Al2O3 spin-echo decay by 50% and inversion-recovery by nearly two orders of magnitude. The theory of satellite transition rotational resonance is presented and the origin of these magic-angle effects is explained.

AB - Satellite transition rotational resonance and magic-angle effects on central-transition spin-echo decay and inversion recovery of half-integer quadrupolar nuclei are presented. Small magic-angle offsets can change the satellite transition rotational resonance condition and consequently lead to dramatic effects on line width, spin-echo decay and inversion recovery. An half degree magic-angle offset lengthens α-Al2O3 spin-echo decay by 50% and inversion-recovery by nearly two orders of magnitude. The theory of satellite transition rotational resonance is presented and the origin of these magic-angle effects is explained.

KW - Quadrupolar nuclei

KW - STMAS

UR - http://www.sciencedirect.com/science/article/pii/S0009261403009588

M3 - Article

VL - 376

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -

Satellite transition rotational resonance of homonuclear quadrupolar spins: magic-angle effect on spin-echo decay and inversion recovery

Abstract

Keywords

Disciplines

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