Third-order effect in solid-state NMR of quadrupolar nuclei

Zhehong Gan; Partha Srinivasan; John R Quine; Stefan Steurnagel; Benno Knott

Third-order effect in solid-state NMR of quadrupolar nuclei

Zhehong Gan, Partha Srinivasan, John R Quine, Stefan Steurnagel, Benno Knott

Florida State University

Research output: Contribution to journal › Article › peer-review

Abstract

The theory and experimental observation of the third-order effect in solid-state NMR of quadrupolar nuclei are presented. The third-order effect consists of spherical harmonic terms up to rank l =6 and shifts NMR frequencies between two spin states that are not symmetric such as satellite transitions. Two-dimensional satellite transition magic-angle spinning experiment averages both the first and the second-order quadrupolar interactions making the quantitative measurement of the third-order effect possible. The third-order quadrupolar effect in andalusite has been measured at 11.7 T and its powder patterns are fitted with numerical simulations.

Original language	American English
Journal	Chemical Physics Letters
Volume	367
State	Published - Jan 2 2003

Keywords

quadrupolar nuclei
third-order effect
solid state NMR

Disciplines

Physical Chemistry

Cite this

@article{7b3bbf671e9a41a49a1822868847bd09,

title = "Third-order effect in solid-state NMR of quadrupolar nuclei",

abstract = " The theory and experimental observation of the third-order effect in solid-state NMR of quadrupolar nuclei are presented. The third-order effect consists of spherical harmonic terms up to rank l =6 and shifts NMR frequencies between two spin states that are not symmetric such as satellite transitions. Two-dimensional satellite transition magic-angle spinning experiment averages both the first and the second-order quadrupolar interactions making the quantitative measurement of the third-order effect possible. The third-order quadrupolar effect in andalusite has been measured at 11.7 T and its powder patterns are fitted with numerical simulations.",

keywords = "quadrupolar nuclei, third-order effect, solid state NMR",

author = "Zhehong Gan and Partha Srinivasan and Quine, \{John R\} and Stefan Steurnagel and Benno Knott",

note = "The theory and experimental observation of the third-order effect in solid-state NMR of quadrupolar nuclei are presented. The third-order effect consists of spherical harmonic terms up to rank l=6 and shifts NMR frequencies between two spin states that are not symmetric such as satellite transitions.",

year = "2003",

month = jan,

day = "2",

language = "American English",

volume = "367",

journal = "Chemical Physics Letters",

}

TY - JOUR

T1 - Third-order effect in solid-state NMR of quadrupolar nuclei

AU - Gan, Zhehong

AU - Srinivasan, Partha

AU - Quine, John R

AU - Steurnagel, Stefan

AU - Knott, Benno

N1 - The theory and experimental observation of the third-order effect in solid-state NMR of quadrupolar nuclei are presented. The third-order effect consists of spherical harmonic terms up to rank l=6 and shifts NMR frequencies between two spin states that are not symmetric such as satellite transitions.

PY - 2003/1/2

Y1 - 2003/1/2

N2 - The theory and experimental observation of the third-order effect in solid-state NMR of quadrupolar nuclei are presented. The third-order effect consists of spherical harmonic terms up to rank l =6 and shifts NMR frequencies between two spin states that are not symmetric such as satellite transitions. Two-dimensional satellite transition magic-angle spinning experiment averages both the first and the second-order quadrupolar interactions making the quantitative measurement of the third-order effect possible. The third-order quadrupolar effect in andalusite has been measured at 11.7 T and its powder patterns are fitted with numerical simulations.

AB - The theory and experimental observation of the third-order effect in solid-state NMR of quadrupolar nuclei are presented. The third-order effect consists of spherical harmonic terms up to rank l =6 and shifts NMR frequencies between two spin states that are not symmetric such as satellite transitions. Two-dimensional satellite transition magic-angle spinning experiment averages both the first and the second-order quadrupolar interactions making the quantitative measurement of the third-order effect possible. The third-order quadrupolar effect in andalusite has been measured at 11.7 T and its powder patterns are fitted with numerical simulations.

KW - quadrupolar nuclei

KW - third-order effect

KW - solid state NMR

UR - http://www.sciencedirect.com/science/article/pii/S0009261402016810

M3 - Article

VL - 367

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -

Third-order effect in solid-state NMR of quadrupolar nuclei

Abstract

Keywords

Disciplines

Other files and links

Cite this